摘要
报道了正戊醇对CTAB/KBr胶束体系流变性的影响.结果表明:在0.01mol·dm^(-3)CTAB(十六烷基三甲基溴化铵)溶液中,正戊醇促使CTAB/KBr胶束体系的粘度增大至一最大值,然后降低.在0.08mol·dm^(-3)CTAB/0.8mol·dm^(-3)KBr的溶液中,正戊醇能促使该胶束体系呈现粘弹性.根据动态荧光法测定的胶束聚集数对以上结果进行了解释.
The effect of n - pentanol on the rheological properties of CTAB/KBr micellar systems has been investigated. The addition of n ?pentanol induces the viscosity of CTAB/KBr micellar system to go through a marked maximum in 0.01 mol·dm-3CTAB/KBr solution. In 0.08 mol ·dm-3CTAB/0.08 mol·dm-3 solution, a small amount of n - pentanol can make CTAB/KBr system have viscoelasticity, when the n - pentanol concentration increases continuously, the viscoelasticity of this micellar system decreases. Finally, we discuss these results in terms of the micellar aggregation number determined from time resolved fluorescence spectrophotometry.
出处
《化学学报》
SCIE
CAS
CSCD
北大核心
2000年第4期374-377,共4页
Acta Chimica Sinica
基金
国家攀登(B)计划(85-33-01)
西南石油学院油气藏地质及开发工程国家重点实验室资助项目
