摘要
可调谐半导体激光吸收光谱技术是一种具有高灵敏度、高选择性的非接触式气体在线测量技术。通过直接扫描多条H2O特征谱线并结合最小二乘算法实现对开放环境气体温度的在线测量。利用HITRAN光谱数据库详细讨论了边界效应对气体温度浓度测量的影响,计算结果表明,扫描多特征谱线并结合最小二乘算法可有效减小边界效应对开放环境气体温度测量的影响。实验中采用时分复用技术同时扫描了7 444.36,7 185.60,7 182.95和7 447.48cm-1四条H2O特征谱线,对管式炉573～973K范围内不同工况下的气体温度进行了测量。吸收光谱测量结果与热电偶信号的最大温差小于52.4K,温度测量最大相对误差为6.8%。
Tunable diode laser absorption spectroscopy（TDLAS） technology is a kind of high sensitivity,high selectivity of non contacting gas in situ measurement technique.In the present paper,in situ gas temperature measurement of an open environment was achieved by means of direct scanning multiple characteristic lines of H2O and combined with least-squares algorithm.Through the use of HITRAN spectral database,the boundary effect on the gas temperature and concentration measurements was discussed in detail,and results showed that the combination of scanning multiple characteristic lines and least-squares algorithm can effectively reduce the boundary effect on the gas temperature measurements under the open environment.Experiments using time division multiplexing technology to simultaneously scan 7 444.36,7 185.60,7 182.95 and 7 447.48 cm-1,the four characteristic H2O lines,the gas temperature of tubular furnace in the range of 573~973 K was measured under different conditions.The maximum temperature difference between absorption spectrum measurement and thermocouple signal was less than 52.4 K,and the maximum relative error of temperature measurement was 6.8%.
出处
《光谱学与光谱分析》
SCIE
EI
CAS
CSCD
北大核心
2012年第5期1329-1333,共5页
Spectroscopy and Spectral Analysis
基金
国家自然科学青年科学基金项目(11002074)
高等学校博士学科点专项科研基金项目(20093219110037)
中国博士后科学基金项目(20100481147)
江苏省博士后科研计划项目(0902094C)
南京理工大学自主科研专项计划项目(2010ZYTS092)资助
