摘要
目的：研究中国南海褐藻Ｓａｒｇａｓｓｕｍ ｖａｃｈｅｌｌｉａｎｕｍ 和绿藻Ｕｌｖａｌａｃｔｕｃａ 的化学成分。方法：应用各种色谱技术进行分离纯化，用ＭＳ，ＩＲ，１ＨＮＭＲ，１３ＣＮＭＲ（ＤＥＰＴ），ＨＭＱＣ和ＨＭＢＣ鉴定化合物。结果：分离并鉴定了２ 个新化合物，化合物１ ｖａｃｈｅｌｌｉｎ 为１１甲基Δ１，５３，７，１０三羰基２，４，８，９四氮环十一二烯，化合物２ｌａｃｔｕｃａｓｔｅｒｏｌ 为胆甾２８甲基２３ ，２４环丙烷Δ５４酮。结论：１ 和２ 为新化合物。
AIM: To study the chemical composition in the alga Sargassum vachellianum and Ulva lactua collected from South China Sea. METHODS: Various column chromatography were used to separate the chemical constituents. MS, IR, 1HNMR, 13 CNMR(DEPT), HMQC and HMBC were used to determine the structure of the isolated constituent. RESULTS: Two new compounds were isolated and their structure were elucidated as 11 methyl 1,5 diene 3,7,10 tricarbonyl 2,4,8,9 tetranitrogen cycloundecandien(1) and cholesta 28 methyl 23,24 cyclopropane Δ 5 4 one 3β ol(2) on the basis of spectral evidence. CONCLUSION: compounds 1 and 2 are new compounds.
出处
《药学学报》
CAS
CSCD
北大核心
2000年第1期26-28,共3页
Acta Pharmaceutica Sinica
基金
广东省自然科学基金!984063
暨南大学前沿科学基金
