摘要
用流动放电—化学发光方法测定O(~3p)原子和丙烯醇分子化学反应速率常数.在293K—473K 范围内,反应速率常数的Arrhenius 形式为k=(6.41_(-0.61)^(+0.67))×10^(-11)exp[-(6.4±0.3)kJ·mol^(-1)/RT]cm^3·molecule^(-1)·s^(-1)并对该反应的反应机理进行了讨论.
The measured data of the second order rate constant of reaction between
O(^(?)p)and allyl alcohol by using discharge flow-chemiluminescence technique
are presented.The Arrhenius expression of the rate constants is as follows
k=(6.41_(-0.61)^(+0.67)×10^(-11)exp(-6.4±0.3)kJ·mol^(-1)/RT)cm^3·molecule^(-1)·s^(-1)
In addition,the mechanism of this reaction is discussed.
