摘要
By using photoacoustic calorimetry, a photoacoustic measurement system is applied to determine the Co-C bond dissociation energy of n C4H9Co(Salen)H2O, which is 116±8kJ·mol-1. This value is in agreement with the activation enthalpy of the Co-C bond homolytic cleavage reaction that obtained by the kinetic method.
By using photoacoustic calorimetry, a photoacoustic measurement system is applied to determine the Co-C bond dissociation energy of n C4H9Co(Salen)H2O, which is 116±8kJ·mol-1. This value is in agreement with the activation enthalpy of the Co-C bond homolytic cleavage reaction that obtained by the kinetic method.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2000年第1期144-146,共3页
Chinese Journal of Inorganic Chemistry
基金
国家自然科学基金资助项目 !(No.19774013和29823001)
关键词
光声量热法
辅酶B12
键离解能
Co-C键
photoacoustic calorimetry model compounds of coenzyme B_(12) bond dissociation energy
