摘要
含活性氧的过氧杂多酸(盐)是由杂多酸(盐)与过量H2O2反应而生成的,其具有高效的催化活性,可以用于催化氧化不同的物质,是一类性能优异的绿色催化剂,其在有机合成中有十分广阔的发展前景。本文介绍了过氧杂多酸(盐)的结构、性质和催化作用,并综述了近年来其在催化有机反应中的研究进展。
Peroxo-heteropolyacid（salt） containing active oxygen was produced by the reaction of heteropolyacids with excess H2O2.It exhibits an interesting catalytic property and has been proved to be useful catalysts for oxidation of different organic compounds.It is a type of the green catalyst with excellent performances and will possess extensive application prospect in organic synthesis.In this paper,its structure,properties and catalysis are introduced and the progress of its catalysis in the organic reaction is reviewed.
出处
《化学通报》
CAS
CSCD
北大核心
2012年第3期239-244,共6页
Chemistry
基金
黑龙江省杰出青年基金项目(B2004-01)资助
关键词
过氧杂多酸(盐)
过氧化氢
催化氧化
有机反应
Peroxo-heteropolyacid（salts）
Hydrogen peroxide
Catalytic oxidation
Organic reaction
