摘要
Reversible assembly and disassembly of rodlike large complex micelles have been achieved by applying photoswitching of supramolecular inclusion and exclusion of azobenzene-functionalized hyperbranched polyglycerol and acyclodextrin as driv ing force, promising a versatile system for selfassembly switched by light. Hydrogennuclear magnetic resonance （H NMR） and Fourier transform infrared （FTIR） spectroscopy were applied to characterize the azobenzenefunctionalized hyperbranched polyglycerol. Atomic force microscopy （AFM）, transmission electron microscopy （TEM） and dynamic laser light scattering （DLS） were employed to investigate and track the morphology of the rodlike large complex micelles before and after irradiation of UV light.
Reversible assembly and disassembly of rod-like large complex micelles have been achieved by applying photoswitching of supramolecular inclusion and exclusion of azobenzene-functionalized hyperbranched polyglycerol and α-cyclodextrin as driving force, promising a versatile system for self-assembly switched by light. Hydrogen-nuclear magnetic resonance (1H NMR) and Fourier transform infrared (FT-IR) spectroscopy were applied to characterize the azobenzene-functionalized hyperbranched polyglycerol. Atomic force microscopy (AFM), transmission electron microscopy (TEM) and dynamic laser light scattering (DLS) were employed to investigate and track the morphology of the rod-like large complex micelles before and after irradiation of UV light.
基金
supported by the National Natural Science Foundation of China (20974093)
the National Basic Research Program of China (973 Program, 2007CB936004)
Qianjiang Talent Foundation of Zhejiang Province (2010R10021)
the Fundamental Research Funds for the Central Universities (2009QNA4040)
Zhejiang Provincial Natural Science Foundation of China (R4110175)
Research Fund for the Doctoral Program of Higher Education of China ( 20100101110049)
