摘要
Fe（III） immobilized fire clay （Fe-FC） was prepared using ferric nitrate by solid state dispersion method and this hetero-Fenton catalyst was applied for the degradation of Acid Violet 7 （AV 7） under natural sunlight. The 26% ferric nitrate loaded fire clay was found to be most efficient. The experimental conditions such as solution pH, H2O2 concentration for efficient degradation of AV 7 have been determined. Unlike Fenton catalyst, Fe-FC is photoactive over a wide pH range of 3-7. This catalyst was found to be stable and reusable. The GC-MS analysis of experimental solutions during irradiation revealed the formation of 2,8-diaminonaphthalene-1,3,6- triol, 8-aminonaphthalene-1,2,3,6-tetrol, 2-aminonaphthalene-1,3,6,8-tetrol and 2-aminobenzene-1,3-diol/5-aminonbenzene-1,3-diol/ 2-aminobenzene-1,4-diol as intermediates. The 26% ferric nitrate loaded fire clay was characterized by XRD, ICP-AES, BET surface area, FT-IR, SEM-EDS and UV-DRS studies.
Fe（III） immobilized fire clay （Fe-FC） was prepared using ferric nitrate by solid state dispersion method and this hetero-Fenton catalyst was applied for the degradation of Acid Violet 7 （AV 7） under natural sunlight. The 26% ferric nitrate loaded fire clay was found to be most efficient. The experimental conditions such as solution pH, H2O2 concentration for efficient degradation of AV 7 have been determined. Unlike Fenton catalyst, Fe-FC is photoactive over a wide pH range of 3-7. This catalyst was found to be stable and reusable. The GC-MS analysis of experimental solutions during irradiation revealed the formation of 2,8-diaminonaphthalene-1,3,6- triol, 8-aminonaphthalene-1,2,3,6-tetrol, 2-aminonaphthalene-1,3,6,8-tetrol and 2-aminobenzene-1,3-diol/5-aminonbenzene-1,3-diol/ 2-aminobenzene-1,4-diol as intermediates. The 26% ferric nitrate loaded fire clay was characterized by XRD, ICP-AES, BET surface area, FT-IR, SEM-EDS and UV-DRS studies.
基金
the Ministry of Environment and Forests (MOEF), New Delhi, for the financial support through research grant No.315-F-36, F. No. 19/9/2007-RE
