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Al-Sc二元合金中次生Al_3Sc的析出和长大行为 被引量:5

Precipitation and Coarsening Behavior of Secondary Al_3Sc Phase in Al-Sc Binary Alloy
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摘要 研究了温度、时间等因素对Al-0.4Sc合金时效过程中次生Al3Sc粒子的析出和长大规律及其对合金性能的影响。指出在350、400和450℃下时效,次生Al3Sc粒子长大行为基本符合Lifshitz-Slyozov-Wagner(LSW)理论预测;在500℃下时效1h,粒子长大行为接近LSW理论预测值,1h以上,粒子长大速度变慢,与LSW理论偏差较大。当Al3Sc粒子半径在4~40nm的范围内,Al-0.4Sc合金硬度值随着粒子尺寸上升而下降;当Al3Sc半径为4~7.5nm时,硬度为750~850MPa,大约是热处理前的硬度值(200MPa)的3.75~4.25倍,析出强化作用显著;当Al3Sc半径达到40nm时,合金硬度下降到300MPa。 The influence of different temperatures and time on the precipitation and coarsening behavior of secondary Al3Sc in the Al-Sc alloy and the role of the secondary Al3Sc in properties of Al-Sc alloy were investigated.It is concluded that the coarsening behavior follows the kinetic law of the Lifshitz-Slyozov-Wagner(LSW) theory with the alloys aged at 350 ℃,400 ℃ or 450 ℃,and it is predicted approximately by the LSW theory at 500 ℃ within 1 hour,however,departed from the LSW theory with a lower coarsening speed at 500 ℃ with aged more than 1 hour.The hardness of Al-Sc alloys is decreased with the particles radius increasing in the range of 4~40 nm.When the radius of Al3Sc is in range of 4 ~7.5 nm,the alloy hardness reaches its peak value of about 750~850 MPa,nearly 3.75~4.25 times of the value before heat treatment,exhibiting significantly precipitating strengthening effects.When the particle radius reaches 40 nm,the alloy hardness reduces to 300 MPa.
出处 《特种铸造及有色合金》 CAS CSCD 北大核心 2012年第3期197-202,共6页 Special Casting & Nonferrous Alloys
基金 高等学校博士学科点专项科研基金资助项目(20050003042)
关键词 AL-SC合金 次生Al3Sc 沉淀析出 长大行为 Al-Sc Alloy Secondary Al3Sc Precipitation Coarsening Behavior
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