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超痕量H_2O_2对MnSO_4-KBrO_3-乙酰丙酮化学振荡体系的扰动 被引量:8

Perturbation Effect of Ultra Trace Hydrogen Peroxide on the MnSO_4-KBrO_3-Diacetone Oscillating Chemical Reaction
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摘要 The similarities between life processes that exhibit oscillatory behavior and chemical oscillating systems impel people to think that the biological and abiological phenomena conform to the same law. Oscillating chemical systems have been the focus of much research in the area of theoretical and experimental chemical dynamics as well as analytical sciences in recent years, but the studies on the perturbation species are kept around the concentration level of 10 -7 mol/L. In our experiment, an amazed phenomenon was found. Ultra trace level (10 -20 mol/L) of H 2O 2 can cause so magnitude influence on the macro system (MnSO 4 KBrO 3 diacetone oscillating chemical system) that the effect can be observed by a macroscopical method. When the concentration of H 2O 2 is above 10 -13 mol/L , the oscillation can even be stopped. A further study on the mechanism will doubtlessly help to understand the mystery of life, such as the sudden cardiopathy and the metabolism failure. The similarities between life processes that exhibit oscillatory behavior and chemical oscillating systems impel people to think that the biological and abiological phenomena conform to the same law. Oscillating chemical systems have been the focus of much research in the area of theoretical and experimental chemical dynamics as well as analytical sciences in recent years, but the studies on the perturbation species are kept around the concentration level of 10 -7 mol/L. In our experiment, an amazed phenomenon was found. Ultra trace level (10 -20 mol/L) of H 2O 2 can cause so magnitude influence on the macro system (MnSO 4 KBrO 3 diacetone oscillating chemical system) that the effect can be observed by a macroscopical method. When the concentration of H 2O 2 is above 10 -13 mol/L , the oscillation can even be stopped. A further study on the mechanism will doubtlessly help to understand the mystery of life, such as the sudden cardiopathy and the metabolism failure.
出处 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2000年第3期377-379,共3页 Chemical Journal of Chinese Universities
基金 国家自然科学基金!(批准号 :2 9775 0 15 )
关键词 化学振荡反应 非线性动力学 过氧化氢 CSTR Oscillating chemical reaction Hydrogen peroxide CSTR(continuous flow stirred tank reactor) Nonlinear kinetics
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参考文献4

  • 1Pojman J. A,Epstein I. R,Mc Manus T. J. et al. The Journal of Physical Chemistry . 1991
  • 2Jiménez-Prieto R,Silva M,Pérez-Bendito D. The Analyst . 1998
  • 3Resch,P.,Field,R. J.,Schneider,F. W. The Journal of Physical Chemistry . 1989
  • 4Field R J,Burger M.Oscillations and Travelling Waves in Chemical Systems[]..1985

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