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配合物中稀土离子的有效磁矩测定 被引量:1

EXPERIMENTAL DETERMINATION OF THE EFFECTIVE MAGNETIC MOMENTS OF RARE EARTH CATIONS IN SOME COMPLEXES
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摘要 In this paper,the μeff’s of RE 3+ in five series complexes were determined by means of the self made Faraday magnetic balance.The experimental lindings show that in complex formation the number of 4f electrons of RE 3+ is increased.This result supports the point of view that the RE 4f orbital participates in covalent bond. In this paper,the μeff's of RE 3+ in five series complexes were determined by means of the self made Faraday magnetic balance.The experimental lindings show that in complex formation the number of 4f electrons of RE 3+ is increased.This result supports the point of view that the RE 4f orbital participates in covalent bond.
出处 《化学研究与应用》 CAS CSCD 2000年第1期103-105,共3页 Chemical Research and Application
关键词 有效磁矩 配合物 稀土离子 磁化率 effective magnetic complex rare earth cation 4f orbital
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  • 1潘道皑,华东师范大学学报,1991年,9卷,化学专辑,135页
  • 2中本一雄,无机和配位化合物的红外和拉曼光谱,1986年
  • 3王春相,生凤兰,纪凤菊.稀土复合氧化物催化剂中镧、钙、锰的测定[J]分析化学,1982(06).
  • 4王则民,朱福森,曹锦荣,王婷.希土萘乙酸固体配合物的合成和表征[J].无机化学学报,1992,8(3):343-345. 被引量:8

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