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甘油制备丙烯醛的最新研究进展 被引量:7

Research progress in glycerol dehydration to acrolein
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摘要 甘油可以通过各种工艺转化为具有高附加值的化工品,其中选择性催化脱水制备丙烯醛是一个重要的利用途径。在综述甘油制备丙烯醛催化剂体系最新研究进展的基础上,分析了该反应体系的反应历程和催化反应机理,讨论了目前该工艺过程中存在的问题,并对其应用前景进行了展望。 Glycerol can be transformed into the desirable and higher valuable chemicals via various technical routes, among which glycerol dehydration to acrolein is an important one. This paper summarizes the research progress achieved in catalyst system, and also discusses the possible pathway and the catalytic mechanism for glycerol dehydration to acrolein. In addition, the current main problems in the technical route are analyzed, and the application prospect is also forecasted.
出处 《现代化工》 CAS CSCD 北大核心 2012年第2期28-32,共5页 Modern Chemical Industry
基金 中国科学院可再生能源与天然气水合物重点实验室基金项目(y107j5)
关键词 甘油 丙烯醛 生物柴油 催化剂 glycerol acrolein biodiesel catalyst
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  • 1Corma A, Huber G W, Sauvanaud L, et al. Biomass to chemicals: Catalytic conversion of glycerol/water mixtures into acrolein reaction network[ J]. Journal of Catalysis,2008,257:163 - 171.
  • 2Buhler W, Dinjus E, Ederer H J, et al. Ionic reactions and pyrolysis of glycerol as competing reaction pathways in near and supercritical water[ J]. Journal of Supercritical Fluids,2002,22:37 - 53.
  • 3Watanabe M, Iida T, izawa Y, et al. Acrolein synthesis from glycerol in hot-compressed water [ J ]. Bioresource Technology, 2007,98 (6) :1285 - 1290.
  • 4Tsukuda E, Sato S,Takahashi R,et al. Production of acerolein from glycerol over silica-supported heteropoly acids [ J ]. Catalysis Communications ,2007,8:1349 - 1353.
  • 5Atia H, Armbruster U, Matin A. Dehydration of glycerol in gas ,hase using heteropolyacid catalysts as active compounds[ J]. Joural of Catalysis ,2008,258 ( 1 ) :71 - 82.
  • 6Chai S H, Wang H P, Liang Y, et al. Sustainable production of acrolein: Gas-phase dehydration of glycerol over 12-tungstophosphoric acid supported on ZrO2 and SiO2 [ J ]. Green Chemistry,2008,10: 1087 - 1093.
  • 7Katryniok B, Paul S, Capron M, et al. A long-life catalyst for glycerol dehydration to acrolein [ J 1- Green Chemistry,2010,12 : 1922 - 1925.
  • 8Erfle S,Armbruster U, Bentmp U,et al. Impact of redox properties on dehydration of glycerol to acmlein over heteropolyacids assessed by operand-EPR spectroscopy [ J ]. Applied Catalysis A : General, 2011,391 : 102 - 109.
  • 9Dubois J L, Duquenne C, Holderich W. Process fordehydration glycerol to acrolein : US ,2008/0214880A1 [ P]. 2008 - 02 - 14.
  • 10Chai S H, Wang H P, Liang Y, et al. Sustainable production of acrolein:Gas-phase dehydration of glycerol over Nb2O5 catalyst [ J ]. Journal of Catalysis,2007,250 (2) : 342 - 349.

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