摘要
简要介绍了六氯环三磷腈的结构和理化性质,研究了五氯化磷与氯化铵反应生成六氯环三磷腈的反应机理,概述了六氯环三磷腈的合成方法以及本课题组的合成进展,综述了其在阻燃领域的应用进展,最后指出了六氯环三磷腈在我国工业化生产中存在的问题和解决途径。
The structure and physicoehemical properties of hexachlorocyclotriphosphazene are briefly intro- duced. The reaction mechanism of hexachlorocyclotriphosphazene, which is synthesized by phosphorus pentachloride and ammonium chloride is investigated. The synthetic method of hexachlorocyclotriphosphazene and progress on syn thesis in our research group are summarized. The progress on applications of hexachlorocyclotriphosphazene as flame retardant is reviewed. At last, the problems in industrial production for hexachlorocyclotriphosphazene and approaches to slove these problems are pointed out.
出处
《材料导报》
EI
CAS
CSCD
北大核心
2012年第5期66-69,共4页
Materials Reports
基金
国家教育部"蓝火计划"(20110941023)
贵州省科学技术基金(黔科合丁字[2011]2074号)
关键词
六氯环三磷腈
合成
阻燃
hexachlorocyclotriphosphazene, synthesis, flame retardent
