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利用超临界水氧化法检测水质总有机碳含量技术研究 被引量:1

Application of Supercritical Water Oxidation in Detecting of Total Carbon Organic
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摘要 利用超临界水氧化与非色散红外法相结合的连续式实验装置,对邻苯二甲酸氢钾水溶液的总有机碳含量进行连续检测,研究了温度、氧化剂浓度等对检测结果的影响.研究表明,红外检测信号与水样中的总有机碳浓度具有良好的线性关系;升高温度有利于提高TOC的转化率,在460℃以上时有机物彻底氧化;增加氧化剂用量也会使TOC的转化率增加,在氧化剂为10倍量(化学计量比1∶1为1倍)时能把溶液中的有机物彻底氧化. A supercriticat water oxidation~ (SCWO) and nondispersive infrared sensor (NDIR) combined continuous-flow reactor is used to detect the total organic carbon (TOC) of potassium acid phthalate solution. The influences of temperature and concentration of oxidant on the detection results are also studied. The conversion of TOC has increased with temperature and kept stable at 460 ~C. The increase of concentration of oxidant has also facilitated the conversion of TO(2 and stable at 10 multiple.
出处 《河南师范大学学报(自然科学版)》 CAS CSCD 北大核心 2012年第1期100-102,共3页 Journal of Henan Normal University(Natural Science Edition)
基金 浙江省自然科学基金(Y5100241) 浙江省质量技术监督系统科研计划项目(20100102) 浙江省博士后科研项目择优资助(浙人社发[2010]326号)
关键词 超临界水氧化法 非色散红外法 总有机碳含量 连续检测 SCWO NDIR TOC continuous detection
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参考文献11

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二级参考文献28

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