摘要
利用变温顺磁共振和变温磁化率方法对所合成的新配合物进行研究,结果表明,300K时,g∥=2.06,g⊥=2.12,g∥<g⊥,Cu(II)离子处于D3h对称性的三角双锥结构中,5～300K范围内,磁性参数2J=0.5cm-1,Cu(II)
A novel nuclear copper(II) complex is studied by variable temperature ESR spectra and susceptibility. The results show that at 300 K g ∥=2.06, g ⊥=2.12, g ∥< g ⊥ each copper(II) ion is in the environment of an almost regular trigonal bipyramidal geometry. In the range of 5～300 K with 2 J =0.5 cm -1 ,there is a weak ferromagnetic interaction between the two copper(II) ions.
出处
《淮海工学院学报（自然科学版）》
CAS
2000年第1期38-41,共4页
Journal of Huaihai Institute of Technology:Natural Sciences Edition
基金
江苏省科委基金和青蓝工程基金!资助项目 (BK9910 7)
关键词
变温顺磁共振
变温磁化率
铜配合物
谱学
variable temperature ESR
variable temperature susceptibility
copper(II) complex
