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Transition metal-templated synthesis of catenanes and rotaxanes

Transition metal-templated synthesis of catenanes and rotaxanes
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摘要 Among the various methods nowadays used to make catenanes and rotaxanes,the metal template synthesis occupies a place of choice,because of its versatility.This contribution shows that,thanks to the richness of their chemistry,metal templates can fulfil multiple functions for the construction of these topologically-interesting molecules,from the entwining or threading of their precursors to the simultaneous catalysis of the interlocking reaction. Among the various methods nowadays used to make catenanes and rotaxanes,the metal template synthesis occupies a place of choice,because of its versatility.This contribution shows that,thanks to the richness of their chemistry,metal templates can fulfil multiple functions for the construction of these topologically-interesting molecules,from the entwining or threading of their precursors to the simultaneous catalysis of the interlocking reaction.
机构地区 ICMUB(CNRS UMR no ISIS
出处 《中国科学:化学》 CAS CSCD 北大核心 2012年第1期125-125,共1页 SCIENTIA SINICA Chimica
关键词 模板合成 过渡金属 轮烷 多功能性 金属模板 化学 催化 分子 catenane, rotaxane, mechanical bond, coordination, template, catalysis
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