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Influence of SiO_3^(2-)Impurity on the Optical Properties of KDP Crystal 被引量:1

Influence of SiO_3^(2-)Impurity on the Optical Properties of KDP Crystal
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摘要 In this paper,potassium dihydrogen phosphate(KDP) crystals were grown in the presence of a series of silicate(SiO32-) impurity concentrations via conventional temperature cooling and rapid growth methods,respectively.It revealed that the SiO32-impurity could lead to the decrease of transmittance at the region of ultraviolet band for pyramidal sectors and slightly increased the transmittance for prismatic sectors.SiO32-could enter into the crystal lattice and create lattice defects,which consequently increased the density of light scatter.The decrease of laser damage threshold was attributed to the lattice defects and the redundant electrons brought by the replacement of SiO32-at the PO43-position. In this paper,potassium dihydrogen phosphate(KDP) crystals were grown in the presence of a series of silicate(SiO32-) impurity concentrations via conventional temperature cooling and rapid growth methods,respectively.It revealed that the SiO32-impurity could lead to the decrease of transmittance at the region of ultraviolet band for pyramidal sectors and slightly increased the transmittance for prismatic sectors.SiO32-could enter into the crystal lattice and create lattice defects,which consequently increased the density of light scatter.The decrease of laser damage threshold was attributed to the lattice defects and the redundant electrons brought by the replacement of SiO32-at the PO43-position.
出处 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2012年第1期105-109,共5页 结构化学(英文)
基金 supported by the National Natural Science Foundation of China (No. 50721002)
关键词 crystal growth DEFECTS optical properties laser damage threshold crystal growth defects optical properties laser damage threshold
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