期刊文献+

无水溶胶凝胶法制备LiFe_(1-x)Co_xPO_4/C正极材料及其性能研究

On Positive Material LiFe_(1-x)Co_xPO_4/C Synthesized by Non-aqueous Sol-gel method and Its Performance
在线阅读 下载PDF
导出
摘要 在无水溶胶凝胶法基础上,以Fe3+盐为铁源,添加聚乙二醇-400作为表面活性剂,制备了掺杂钴的LiFePO4/C正极材料(LiFe1-xCoxPO4/C,x=0,0.05,0.1)。并通过XRD、SEM、恒流充放电等方法研究了不同钴掺杂量对LiFePO4/C结构、形貌和电化学性能的影响。 LiFe1-xCoxPO4/C ( x = 0, 0.05, 0.1 ), positive material was synthesized for Li - ion batteries by sol - gel method with Fe (III) salt as Fe source and with PEG - 400 as assistant. The effect of different amount of Co. or, the crystal structure, morphology and electrochemical performance of the samples of LiFePO4/C were studied by XRD, SEM and galvanostatic charge -discharge methods.
出处 《绵阳师范学院学报》 2011年第11期71-73,82,共4页 Journal of Mianyang Teachers' College
关键词 溶胶-凝胶法 钴掺杂 正极材料 电化学性能 sol - gel method positive materials cobalt doping electrochemical performance
  • 相关文献

参考文献6

  • 1Doeff M M, Wilcox J D, Kostecki R, et al. Optimization of carbon coatings on LiFePO4[J]. Journal of Power Sources, 2006 , 163 : 180 - 184.
  • 2M Piana, B L Cushing, J B Goodenough, et al. A new promising sol - gel synthesis of phospho - olivines as environmentally friendly cathode materials for Li -ion ceUs[J]. Solid state Ionics. 2004, 175(14) : 233 -237.
  • 3郑洪河,石磊,赵扬,徐仲榆.锂离子电池纳米正极材料[J].化学通报,2005,68(8):591-600. 被引量:10
  • 4李旭,彭文杰,李新海,王志兴,郭华军.LiFe_(1-x)Mg_xPO_4的制备及其电化学性能[J].中国有色金属学报,2008,18(6):1123-1128. 被引量:6
  • 5PADHI A K, NANJUNDASWAMY K S, GOODENOUGH J B. Phospho - olivines as positive - electrode ma- terials for reckargeable lithium batteries[ J]. J Electrochem Soc, 1997, 144(4) : 1188 - 1194.
  • 6陈西知,吴秋芳,马新胜.纳米材料在锂电池正极材料中应用的研究进展[J].材料导报,2010,24(21):38-44. 被引量:5

二级参考文献87

共引文献18

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部