摘要
以羧基化多壁碳纳米管为原料,经酰氯化、酰胺化和霍夫曼消去反应制备了氨基化多壁碳纳米管,并与己二酸己二胺盐进行了原位聚合反应,还采用透射电子显微镜(TEM)、傅里叶变换红外光谱仪(FTIR)、拉曼光谱仪、热重分析仪(TG)和X-射线光电子能谱仪等对产物进行了表征.结果表明:氨基化多壁碳纳米管每1 000个表面碳原子中有91个转化为氨基,但氨基化多壁碳纳米管的热稳定性较多壁碳纳米管显著下降;聚己二酸己二胺功能化氨基化多壁碳纳米管复合材料的成功制备,表明碳纳米管上的氨基仍具有缩聚反应活性.
The amino multi-walled carbon nanotubes （AMWNT） are fabricated taking carboxylic MWNTs as raw materials by acylchlorides, amidation and Hoffman degradation. The product reacts with adipic acid-hexamethylene diamine salts by in situ polymerization. Transmission Electronic Microscopy （TEM）, Fourier Transform Infrared Spectroscope （FTIR）, Raman Spectroscope, Themaogravimetric Analysis （TG） and X -ray Photoelectron Spectroscopy （XPS） are used to characterize the structure and properties of AMWNT and nanocomposite. The results show that： Amino group is linked to the surface of MWNTs and approximately 91 of every 1 000 carbon atoms on the surface of MWNTs are transformed into amino groups ; however, the thermal stability of AMWNT is inferior to that of MWNTs ; poly （adipic acid-hexamethylene diamine） functionalized AMWNT nanocomposites are fabricated successfully by in situ polymerization of AMWNT and adipic acid-hexamethylene diamine salts and it illustrates that the amino groups on MWNT are polycondensation reactive.
出处
《天津工业大学学报》
CAS
北大核心
2011年第6期9-14,共6页
Journal of Tiangong University
基金
天津市应用基础与前沿重点研究计划项目(09JCZDJC22300)
天津市高等学校科技发展基金计划项目(2006ZD39)
