摘要
Transparent, luminescent and functional nanocomposites demonstrate interesting optical and mechanical properties suitable for many optoelectronic applications. Transparent polymethyl methacrylate （PMMA） polymer nanocornposites modified with thenoyl- trifluoroacetonate （TAA） were fabricated by in situ polymerization and used as hosts for homogenous dispersion of 3 mol.% Eu^3＋：Ca10（PO4）6（OH）2 （Eu^3＋：HA） hydroxyapatite -20 nm large nanocrystals. The emission, excitation and transmission spectra as well as the fluorescence decay rates of bare Eu^3＋：HA nanocrystallites, Eu^3＋：HA embedded in the PMMA and and Eu：HA embedded in the PMMA/TTA rtanocomposites were studied. The improvement of transparency was demonstrated with the addition of TTA as well as europium doped hydroxyapatites in comparison to pure PMMA matrix. The Judd-Ofelt analysis of f-f transitions of Eu^3＋：HA nanocrystallites, the PMMA/Eu^3＋：HA and the PMMA＋TTA/Eu^3＋：HA was performed to investigate the optical behavior of the polymeric composites.
Transparent, luminescent and functional nanocomposites demonstrate interesting optical and mechanical properties suitable for many optoelectronic applications. Transparent polymethyl methacrylate （PMMA） polymer nanocornposites modified with thenoyl- trifluoroacetonate （TAA） were fabricated by in situ polymerization and used as hosts for homogenous dispersion of 3 mol.% Eu^3＋：Ca10（PO4）6（OH）2 （Eu^3＋：HA） hydroxyapatite -20 nm large nanocrystals. The emission, excitation and transmission spectra as well as the fluorescence decay rates of bare Eu^3＋：HA nanocrystallites, Eu^3＋：HA embedded in the PMMA and and Eu：HA embedded in the PMMA/TTA rtanocomposites were studied. The improvement of transparency was demonstrated with the addition of TTA as well as europium doped hydroxyapatites in comparison to pure PMMA matrix. The Judd-Ofelt analysis of f-f transitions of Eu^3＋：HA nanocrystallites, the PMMA/Eu^3＋：HA and the PMMA＋TTA/Eu^3＋：HA was performed to investigate the optical behavior of the polymeric composites.
基金
Project supported by Polish Ministry of National Education (N N507 584938)
