摘要
利用水热反应合成一种新型含钒氧链阴离子的苯基三联吡啶钴配合物{[Co(PhTPY)2]V3O9.3H2O}n(PhTPY=4′-ph-2,2′∶6′,2″-terpyridine)。用元素分析、红外光谱和X-射线单晶衍射对其结构进行了表征,该配合物晶体属单斜晶系,C2/c空间群。同时测定了配合物的热稳定性、荧光性质和磁性质。
A phenyherpyridyl cobalt(Ⅲ) complex with vanadium-oxygen chain anion {[Co(PhTPY)2]V3O9·3H2O}n(PhTPY =4'-ph-2,2':6',2”-terpyridine)was synthesized under the hydrothermal condition. The structure wascharacterized by elemental analysis, IR and X-ray belongs to monoclinic system, space group C2/c. single crystal diffraction. The crystal structure of the complex Thermal stability, photoluminescence property and magnetic susceptibility of the complex have been investigated. CCDC: 773121.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2012年第1期62-66,共5页
Chinese Journal of Inorganic Chemistry
基金
河南省教育厅自然科学基金(No.2011B150026)资助项目
关键词
钴配合物
晶体结构
磁性质
热稳定性
发光性质
cobalt(Ⅲ) complex
crystal structure
magnetic property
thermal stability
luminescence property