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Sm_2O_3填充碳纳米管/磁性金属微粉双层吸波复合材料的制备与吸波性能 被引量:1

Preparation and microwave absorbing properties of rare-earth Sm_2O_3 filled carbon nanotubes/magnetic metal/epoxy double-layer absorbing composite
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摘要 通过湿化学法制备了Sm2O3填充碳纳米管吸收剂,并依据传输线理论和阻抗匹配原则,设计制备了环氧树脂基Sin203填充碳纳米管/磁性金属微粉双层结构吸波复合材料.采用透射电镜、扫描电镜和X射线衍射分析对Sin2O3填充碳纳米管和磁性金属微粉的微观形貌和结构进行了分析,HP8722ES矢量网络分析仪测量了材料在2~18GHz频率范围内的吸波特性.研究表明:与未填充碳纳米管相比,Sm2O3填充碳纳米管的磁损耗正切增大,吸收频带变宽,同时吸收峰由C波段迁移到中频X波段.这种双层结构吸波复合材料具有较好的宽频带吸波效果,其匹配厚度为dm=5.0mm时,在2.8和14.2GHz处有两个吸收峰,反射率小于-10dB的频宽为0.98GHz,反射率低于-5dB的频宽达6.46GHz,在S波段均低于-5dB. Rare-Earth Sm2O3filled carbon nanotubes were prepared by wet chemistry solution method. According to the transmission line theory and impedance matching principal, a kind of double-layer absorbing composite was prepared. The surface layer and last layer are composed of Sm2O3 filled multiwalled carbon nanotubes (Sm2O3-MWCNTs) and the magnetic metal powder, respectively. Sm2O3- MWCNTs and magnetic metal powder were characterized by TEM, SEM and XRD. The microwave absorbing properties of the composites were measured in the frequency range of 2-- 18 GHz. Compared with the unfilled MWCNTs, the absorbing peaks of Sm2O3-MWCNTs moves to the higher frequency and the absorbing bandwidth was widened. The results of experimental measurement show that the double-layer composite has good absorbing performance in low frequency region. There are two absorbing peaks in the frequency range of 2-18GHz with the matching thickness of 5.0 mm, correspondingly, the bandwidth below-10 dB and -5dB is 0.98 GHz and 6.46 GHz.
出处 《北京交通大学学报》 CAS CSCD 北大核心 2011年第6期112-116,共5页 JOURNAL OF BEIJING JIAOTONG UNIVERSITY
基金 河南省教育厅自然科学研究计划项目资助(2011A430017) 洛阳理工学院引进人才专项科研基金项目资助(2009BZ20)
关键词 稀土 多壁碳纳米管 磁性金属微粉 双层结构复合材料 吸波性能 rare-earth multi-walled carbon nanotubes magnetic metal powder double-layer composites microwave absorbing properties
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