摘要
以银离子、3,3′,4,4′-二苯硫酮四羧酸阴离子(tdpc)和4,4′-联吡啶(bipy),合成了一种新型化合物[十二水合(3,3,′4,4′-二苯硫酮四羧酸)(4,4′-联吡啶)水合银][Ag2(tdpc)(bipy)2][Ag2(bipy)2(H2O)].12H2O,该化合物为链状结构,Ag…Ag相互作用,bipy间的π-π相互作用和氢键作用将化合物联接为三维超分子结构.
A novel compound [Ag2(tdpc)(bipy)2][Ag2(bipy)2(H2O)]·12H2O has been synthesized from AgNO3,4,4′-thiodiphthalic acid(H4tdpc) and 4,4′-bipyridine(bipy).The compound shows a 1D chain structure.The Ag…Ag interactions,π-π interactions among bipy ligands and hydrogen-bonds extended the structure into a 3D supramolecular structure.
出处
《分子科学学报》
CAS
CSCD
北大核心
2011年第6期435-438,共4页
Journal of Molecular Science
关键词
银离子
四羧酸
联吡啶
晶体结构
配合物
Ag(Ⅰ)
tetracarboxylate
bipyridine
crystal structure
compound