期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

TiO_2纳米管的“兼并”现象及机理分析

Formation Mechanism of Merger of Titania Nanotube Arrays via Anodization
在线阅读 下载PDF
导出
摘要 采用电化学阳极氧化法制备了高度有序TiO2纳米管阵列,并提出纳米管"兼并"的概念。结合FE-SEM分析并验证了Macak等人提出的pH值梯度理论,并在此基础上用双电层理论解释了"兼并"的形成机理,同时解释了初期纳米管管径进一步增大的原因。 In this article, highly ordered TiO2 nanotube arrays were prepared by electrochemical anodization. The concept of ＇ mergers＇ was proposed, pH gradient theory put forward by Macak was verified with SEM images and the formation mechanism of ＇ mergers＇ of titania nanotubes was explained by the effect of electric double layer. The reasons of the further augment of original nanotubes diameters were also analyzed.
作者 杨硕 刘冠鹏 刘喜波 薛建强 张雪凤
机构地区 中国船舶重工集团公司第七二五研究所
出处 《材料开发与应用》 CAS 2011年第6期37-41,52,共6页 Development and Application of Materials
关键词 阳极氧化 TIO2纳米管 纳米管的“兼并” pH值梯度 双电层效应 Anodic oxidation TiO2 nanotube ＇ Mergers＇ of nanotubes pH value gradient Double electric layer effect
分类号 O646 [理学—物理化学]
  • 相关文献

参考文献13

  • 1Sumio Iijima. Helicalmicrotubules of graphitic carbon [J]. Nature, 1991, 354:56-58.
  • 2Dawei G, Grimes C A, Varghese O K, et al. Titanium oxide nanotube' arrays prepared by anodie oxidation[J]. Mater Res Soc, 2001, 16(12): 3331 - 3334.
  • 3Adachi M, Murata Y, Okada I, et al. Formation of titania nanotubes applications for dye-sensitized solar eeUs[ J ]. Electrochem Soc, 2003, 150 (8) : G488 - G493.
  • 4Uchida S, Chiba R, Masaki N, et al. Rheology and optimization of titania paste for dye-sensitized solar cell [ J ] . Electrochemistry, 2002, 70 ( 6 ) : 466 - 469.
  • 5Varghese O, Gong D W, Grimes C A, et al. Hydrogen sensing using titania nanotubes [ J ]. Sensors Ac- tuators B : Chemical, 2003, 93 ( 1 - 3 ) : 338 - 344.
  • 6赖跃坤,孙岚,左娟,林昌健.氧化钛纳米管阵列制备及形成机理[J].物理化学学报,2004,20(9):1063-1066. 被引量：82
  • 7Mor G K, Oomman K V, Maggie P, et al. Fabrication of tapered, conical-shaped titania nanotubes[ J]. J Mater Res, 2003, 18( 11 ) :2588 -2593.
  • 8Cai Q Y, Panlose M, Varghese O K, et al. The effect of electrolyte composition on the fabrication of self-organized titanium oxide nanotube arrays by anodic oxidation. J Mater Res, 2005, 20( 1) : 230 - 236.
  • 9Mor G K, Oomman K V, Paulose M, et al. A review on highly ordered, vertically oriented TiO2 nanotube arrays : fabrication, material properties and solar energy applications [ J ]. Solar Energy Materials & Solar Cells, 2006, 90 : 2028.
  • 10Bai J, Zhou B X, Li L H, et al. The formation mechanism of titania nanotube arrays in hydrofluoric acid electrolyte [ J ]. J Mater Sci, 2008, 43 ( 6 ) : 1880 - 1884.

二级参考文献21

  • 1姚红军,汪荣昌,戎瑞芬,徐飞,金海岩.TiO_2薄膜氧敏特性研究[J].半导体技术,1997,13(1):50-53. 被引量：6
  • 2Yu J C,Yu J G,Zhao J C.Enhanced photocatalytic activity of mesoporous and ordinary TiO2 thin films by sulfuric acid treatment.Applied Catalysis B:Environmental,2002,36:31
  • 3Yoshimura K,Miki T,Tanemura S.TiO2 electrochromic thin films by reactive direct current magnetron sputtering.J Vac Sci Technol A,1997,15(5):2673
  • 4Mishra P R,Shukla P K,Singh A K,et al.Investigation and optimization of nanostructured TiO2 photoelectrode in regard to hydrogen production through photoelectrochemical process.Inter J Hydrogen Energy,2003,28:1089
  • 5Grant C D,Schwartzberg A M,Smestad G P,et al.Characterization of nanocrystalline and thin film TiO2 solar cells with poly (3-undecyl-2,2,-bithiophene) as a sensitizer and hole conductor.J Electroanalytical Chem,2002,522:40
  • 6Yun H S,Miyazawa K C,Honma I,et al.Synthesis of semicrystallized mesoporous TiO2 thin films using triblock copolymer templates.Mater Sci Eng C,2003,23:487
  • 7Nakanishi K.Pore structure control of silica gels based on phase separation.J Porous Mater,1997,4:67
  • 8Fernandez A,Lassaletta G,Jimenez W M,et al.Preparation and characterization of TiO2 photocatalysts supported on various rigid supports (glass,quartz and stainless steel):Comparative studies of photocatalytic activity in water purification.Appl Catal B:Environ,1995,7:49
  • 9Zanoni R,Righini G,Montenero A,et al.XPS analysis of sol-gel processed doped and undoped TiO2 films for sensors.Surf Interface Anal,1994,22(1):376
  • 10Asahi,R.;Morikawa,T.;Ohwaki,T.;Aoki,K.;Taga,Y.Science,2001,293:269

共引文献89

材料开发与应用
2011年 第6期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部