摘要
提出了Slater径向积分参数沿Rydberg系列展开的方法,根据由此得到的ClⅦ2s^22p^5nf(n=7,8,9,10)组态的有关参数。在组态相互作用理论下,计算了这些组态的能级和波函数分量。结果与已有的一些观测能级符合得非常好。
Variation regularities of Slater radial-integral parameters along a Rydberg series is proposed. From the regularities, all the parameters of the 2s2 2p5nf (n=7,8,9,10) configurations for ClⅦ are determined. The energy-levels and wavefunctions are further predicted within the framework of configuration interaction theory. The results are well in agreement with a few observed values that exist.
出处
《原子与分子物理学报》
CAS
CSCD
北大核心
1990年第3期1541-1548,共8页
Journal of Atomic and Molecular Physics
