摘要
1973年,Ferraris等首次合成了有机导体四硫富瓦烯的复合物(TTF-TCNQ),其室温的电导率高达10~3Ω^(-1)cm^(-1),从而引起了人们对有机导体这一研究领域的重视。人们普遍认为要进一步提高其导电性,必须减少体系的库仑斥力,增加分子间的作用力,提高体系的维数。按此观点,1980年,Jerome等合成了四甲基四硒富瓦烯(TMTSeF)的电荷转移复合物,
A new electron donor-tetrapropionitrilylthiochalcogefulvalene has been prepared. Ithas been studied with cyclic voltammetry and showed clearly that it has two single electrontransfer reversible oxidation-reducing wave. TPT-TTF is stabler than TTF with respect toenergy. It has been studied with electronic absorption spectra and manifested clearly that theenergy difference between TPT-TTF's π-orbital is smaller than the one between BEDT-TTF'swhich has good electric conductivity.
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
1990年第6期535-538,共4页
Chinese Journal of Organic Chemistry
