摘要
介绍邻甲苯胺的电化学合成新方法及其阴极反应机理的研究.为了找出最佳电解电位范围,在电解进行之前,均需先测出每种溶液体系的极化曲线.其产品收率为80%,电流效率为98%.作者经反复试验已推测其阴极反应机理为EEC三个分步,并指出电合成效果与电极反应机理间的关系.
In this paper a new process for the electrochemical synthesis of ortho amino toluene and a study of its oathodio reaction mechanism are introduced. For the sake of seeking out an optimum electrolytic potential, polarization curves of the solutions must be determined before electrolysis. Its product yield andourrent efficiency are 80% and 98% respectively.From repeated trials, the author has deduced that its cathodio reaction mechanism is a three-step EEC, and has pointed out the relations between electro-synthesis and its electrode reaction mechanism.
出处
《应用科学学报》
CAS
CSCD
1990年第4期326-332,共7页
Journal of Applied Sciences
