摘要
The title complex has been synthesized with 2,2＇-biphenyl dicarboxylic acid and 1,10-phenanthroline（phen）in the solvent mixture of water and methanol.It crystallizes（C38H28CuN4O6,Mr = 700.1）in triclinic,space group P1 with a = 1.0868（2）,b = 1.2175（2）,c = 1.6206（3）nm,α = 110.161（2）,β = 102.605（3）,γ = 93.667（2）o,V = 1941.6（6）nm3,Dc = 1.198 g/cm3,Z = 2,F（000）= 722,R = 0.0558 and wR = 0.1208.The crystal structure shows that the copper atom is coordinated with one oxygen atom from 2,2＇-bphenyl dicarboxylic acid molecule and four nitrogen atoms from two 1,10-phenanthroline molecules,forming a distorted square-pyramidal coordination.The TG analysis shows that the title complex is stable under 160.0 ℃.
The title complex has been synthesized with 2,2＇-biphenyl dicarboxylic acid and 1,10-phenanthroline（phen）in the solvent mixture of water and methanol.It crystallizes（C38H28CuN4O6,Mr = 700.1）in triclinic,space group P1 with a = 1.0868（2）,b = 1.2175（2）,c = 1.6206（3）nm,α = 110.161（2）,β = 102.605（3）,γ = 93.667（2）o,V = 1941.6（6）nm3,Dc = 1.198 g/cm3,Z = 2,F（000）= 722,R = 0.0558 and wR = 0.1208.The crystal structure shows that the copper atom is coordinated with one oxygen atom from 2,2＇-bphenyl dicarboxylic acid molecule and four nitrogen atoms from two 1,10-phenanthroline molecules,forming a distorted square-pyramidal coordination.The TG analysis shows that the title complex is stable under 160.0 ℃.
基金
Supported by the Natural Science Foundation of Hunan Province (No.11JJ9006)
Science and Technology Committee of Hunan Province (2009FJ3101)
Science and Technology Committee of Hengyang (2011kj25)
