摘要
以菲咯啉二酮、苯甲醛及其衍生物和醋酸铵为原料,采用无溶剂绿色研磨工艺,合成了芳基咪唑并菲咯啉化合物.通过对不同反应条件的筛选,得到一条高效、简便、绿色的合成芳基咪唑并菲咯啉化合物路线,不同的芳醛与菲咯啉二酮都可以较高的收率得到相应的芳基咪唑并[4,5-f][1,10]菲咯啉.
A facile procedure for the synthesis of 2-phenyl-imidazo-[4,5-J][1,10]phenanthroline derivatives starting from 1,10-phenanthrolinedione, aromatic aldehyde and ammonium acetate was reported. By screening the different reaction conditions, the reactions were carried out with catalyst-free and solvent-free in good yields, environmental benign, as well as convenient operation. The corresponding imidazo-[4,5-J][1,10]- phenanthroline was obtained in good yield by the reaction of aromatic aldehyde with 1,10-phenanthrolinedione.
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
2011年第8期1286-1289,共4页
Chinese Journal of Organic Chemistry
基金
国家自然科学基金(No.20876148)
浙江省自然科学基金(No.Y407306)
2009年国家大学生创新性试验计划(No.091033701)资助项目
关键词
菲咯啉二酮
无溶剂研磨
无催化剂
芳基咪唑并菲咯啉
phenanthrolinedione
solvent-free mulling
catalyst-free
imidazo-[4,5-J][1,1 O] phenanthroline
