摘要
以3,5-二甲基吡唑和硝酸铜为原料合成三(3,5二甲基吡唑)硝酸铜,并用X-射线单晶衍射方法对其进行了晶体结构解析,结果表明,该化合物的晶胞参数为:a=12.5650(14),b=11.5592(13),c=29.944(3),V=4349.1(8)3,Z=8,Dc=1.454 mg/m3,F(000)=1976,T=293(2)K,R1=0.0618,wR2=0.1601。晶体的空间结构被N-H…O分子间和分子内氢键稳定。
Reaction of 3,5-dimethylpyrazole with copper（Ⅱ） salts yields new mononuclear CuL3（NO3）2 coordination compound,where L-（3,5-dimethylpyrazole）.The crystal and molecular structure for the compound was determined by single-crystal X-ray diffraction.The structure is very close to regular square-pyramidal a with CuN3O2 chromophore formed by three L and two NO3-ligands,giving a trigonal distortion parameter（τ）of 0.094.The result showed that the compound was Orthorhombic,Pbca,a = 12.5650（14）？,b = 11.5592（13）？,c = 29.944（3）？,V = 4349.1（8）？^3,Z=8,Dc=1.454 Mg/^m3,F（000）= 1976,T=293（2） K,R1 = 0.0618,wR2 = 0.1601.The complex formed three-dimensional framework through N-H…O intermolecular and intramolecular hydrogen bonds.
出处
《潍坊学院学报》
2011年第2期69-73,共5页
Journal of Weifang University
基金
山东省自然科学基金项目(Y2008B23)
关键词
三(3
5-二甲基吡唑)硝酸铜
合成
结构表征
bis（nitrato-O）-tri（3
5-dimethyl-1H-pyrazole-κN2） copper（Ⅱ） nitrate
synthesis
structure characterization
