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N-对氯苯基马来酰亚胺与苯乙烯聚合的研究

STUDY ON THE COPOLYMERIZATION OF N P CHLOROPHENYL MALEIMIDE WITH STYRENE
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摘要 乙醇作溶剂,考察了引发剂浓度、单体浓度、聚合时间、聚合温度、引发剂类型对N-对氯苯基马来酰亚胺与苯乙烯的共聚活性的影响,得到最佳聚合条件。通过GPC分析,测得共聚物分子量。通过红外、核磁共振的测定,证明N-对氯苯基马来酰亚胺与苯乙燃聚合时能有效地打开双键。 The activity of copolymerization system of N p chlorophenyl maleimide with styrene was systematically studied. Ethanol as solvent, we received the optimum polymerization condition of initiator concentration, monomor concentration, polymerization time, polymerization temperature and initiator type. By GPC analysis, the molecular weight of the copolymer were testified. The results of Infra red and Nuclear Magnetic Resonant analysis illustrated that the double bond of N p chlorophenyl maleimide was splitted when polymerizing with styrene, and the copolymerization was carried out in the way of alternation.
作者 王娟 贺继东
出处 《青岛大学学报(工程技术版)》 CAS 1999年第4期19-23,共5页 Journal of Qingdao University(Engineering & Technology Edition)
关键词 苯乙烯 聚合物 耐热改性剂 N p chlorophenyl maleimide styrene
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  • 1贺继东 王娟 等.四种N-对位取代苯马基来酰亚胺系列化合物的合成[J].石化技术与应用,1999,17(2):11-11.

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