摘要
密度法测定了298.15K下乙醇、环己烷、三氯甲烷、甲苯、丙酮、四氯化碳、乙腈、二甲基甲酰胺、二甲基亚砜在甲醇或苯及两者混合物中的无限稀释偏摩尔体积.密度测定所用溶液中溶质的浓度范围是0.2一1.5m;甲醇和苯混合物是全组成比范围.溶质偏摩尔体积随甲醇-苯组成比的变化趋势反映了几种分子间相互作用结果即三种分子间物理型分子间相互作用;溶质与甲醇分子氢键缔合相互作用;溶质同甲醇或苯的弱络合作用。
Partial molal volumes of ethanol, cyclohaxane, trichloromethane, toluene, acetone,carbon tetrachloride, acetonitrile, DMF, and DMSO in methanol, benzene, and theirmixtures at infinite dilution at 298.15K were determined with density measurement.The concentration of solutes for density measurement is in the range from 0.2 to 1.5mol.kg^(-1) solvent. The compositions of methanol-benzene mixture lay between molefraction 0 and 1. Variation of solute partial molal volumes with composition ofmethanol-benzene mixture was attributed to several aspects of molecular interaction, i. e.physical type interaction among three kinds of molecules; hydrogen bond associationbetween solute and methanol molecules; and weak complex between solute and methanolor benzene.
出处
《物理化学学报》
SCIE
CAS
CSCD
北大核心
1990年第4期485-490,共6页
Acta Physico-Chimica Sinica
基金
国家自然科学基金
