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Cu掺杂对(K_(0.5)Na_(0.5))NbO_3-(Bi_(0.5)Na_(0.5))TiO_3-LiSbO_3-NaTaO_3系压电陶瓷结构及性能的影响

STUCTURE AND ELECTRICAL PROPERTIES OF Cu-DODED (K_(0.5)Na_(0.5))NbO_3-(Bi_(0.5)Na_(0.5))TiO_3-LiSbO_3-NaTaO_3 LEAD-FREE PIEZOELECTRIC CERAMICS
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摘要 采用传统的陶瓷工艺制备了0.94[0.9405(K0.5Na0.5)NbO3-0.0095(Bi0.5Na0.5)TiO3-0.05LiSbO3]-0.06NaTaO3(简称KNN-BNT-LS-NT)+xmol%CuO(0≤x≤2.0)陶瓷,研究了其晶体结构、压电、介电以及铁电性质,并对Cu2+在A、B位取代做了详细的分析讨论。结果表明,Cu2+的加入能显著提高陶瓷的机械品质因数Qm和降低其介电损耗tanδ,当加入1.5mol%的Cu2+在时,取得较佳的性能,即d33=183pC/N、Qm=166、tanδ=0.0135。 The 0.94[0.9405(K0.5Na0.5)NbO3-0.0095(Bi0.5Na0.5)TiO3-0.05LiSbO3]-0.06NaTaO3(abbreviated as KNN-BNT-LS-NT)+xmol%CuO(0≤x≤2.0) lead free piezoelectric ceramics were prepared by conventional solid state reaction technique. The effects of Cu^2+ on the crystal structure, piezoelectric, dielectric and ferroelectric properties of the ceramics were investigated, A detailed analysis that Cu^2+ had substituted for A and B site cations had been given. The result indicated that Cu^2+ doping more improved the mechanical quality factor (Qm) and decreased the dielectric loss (tan δ ). A specimen doped with 1.5mol% Cu^2+ exhibited the best electrical properties, that d33=183pC/N, Qm=166, tanδ =0.0135.
出处 《中国陶瓷》 CAS CSCD 北大核心 2011年第6期31-34,42,共5页 China Ceramics
关键词 压电陶瓷 钙钛矿 Cu^2+-掺杂 机械品质因数 piezoelectric ceramics, perovskite, Cu^2+-doped, mechanical quality factor
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