摘要
本文提供了制备固体过氧钼酸的新方法,它以Na_2MoO_4为原料,按Mo:H_2O_2=2.00:1.05(摩尔比)和游离酸度为0.40mole/dm^3的量加入H_2O_2和HNO_3,然后在50℃条件下加热20小时,析出Mo:(O_2):H_2O=2:1:2的固体过氧钼酸,得率96%。用热分析和超高真空程序升温质谱研究了它的性质,并推断其可能结构。
A new method is purposed for the preparation of peroxomolybdic acid in this paper. The reaction proceeded for 20 hours at 50℃ using H2O2 as complex agent, Na2MoO4 as starting material (Mo:H2O2 = 2.00:1.05) and the free acidity of solution was 0.40 mole HNO3 / dm3.The yield was 96%.Its chemical component shows the ratio Mo:(O2):H2O = 2:1:2. The physical properties of the acid were studied by thermal analysis and mass spectroscopy detection, and the structure of this compound has also been inferred.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
1990年第3期295-298,共4页
Chinese Journal of Inorganic Chemistry
关键词
过氧钼酸
聚过氧钼酸
peroxomolybdic acid poly-peroxomolybdic acid
