摘要
本文报道了六种含ida,edma及dien的Cu-Im-Co,Cu-Im-Pt,Co-Im-Cu-Im-Co和Co-Im-Zn-Im-Co异双核,异三核配合物的合成与表征。用~1H NMR及反射光谱证实配合物中咪唑桥的存在,并对配合物中Cu的空间构型及成键性质进行了讨论。
Six new heteropolynuclear complexes containing tridentate ligand , ida and edma, were synthesized and characterized. The imidazolate bridges in the title complexes were ascertained by NMR and reflectance spectroscopies.The configuration and bonding character of the complexes are discussed.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
1990年第2期198-203,共6页
Chinese Journal of Inorganic Chemistry
关键词
铜
锌
咪唑桥
异多核配合物
imidazolate bridged beteropolymuclear complexcs copper zime