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超临界二氧化碳中聚氟乙烯的制备 被引量:1

Polymerization of Polyvinyl Fluoride in Supercritical Carbon Dioxide
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摘要 以超临界二氧化碳为介质进行氟乙烯单体的聚合.结果表明在超临界二氧化碳中氟乙烯单体的聚合反应更平稳,所得聚合物规整度更高. Using supercritical carbon dioxide as the medium, the experiment polymerized vinyl fluoride. The results show that the homopolymerization of vinyl fluoride in supercritical carbon dioxide is more steadily, the tacticity of polymer is better.
出处 《杭州师范大学学报(自然科学版)》 CAS 2011年第3期258-261,267,共5页 Journal of Hangzhou Normal University(Natural Science Edition)
关键词 超临界二氧化碳 氟乙烯 聚氟乙烯 均聚 supercritical carbon dioxide vinyl fluoride polyvinyl fluoride homopolymerization
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参考文献9

  • 1李虹,徐安厚,张永明.超临界二氧化碳中含氟聚合物的合成[J].化学进展,2007,19(10):1562-1567. 被引量:13
  • 2Avila D V,Ingold K U,Lusztyk J,et al.Absolute rate constants for some reactions of perfluoro-n-alkyl radicals in solution[J].J Am Chem Soc,1994,116 (1):99-104.
  • 3张艳中,蒋争光.一种聚氟乙烯的制备方法:中国,1834124[P].2006-09-20.
  • 4Ovenall D W,Uschold R E.Detection of branching on poly(vinyl fluoride) by NMR and the effect of synthesis conditions on polymer structure[J].Macromolecules,1991,24(11):3235-3237.
  • 5张艳中,李小年,蒋争光,马培良.聚乙烯/聚丙烃催化合金的组成分析[J].浙江工业大学学报,2005,33(6):618-622. 被引量:3
  • 6Guan Zhibin,Combes J R,Menceloglu Y Z,et al.Homogeneous free radical polymerizations in supercritical carbon dioxide 2:thermal decomposition of 2,2′-azobis(isobutyronitrile)[J].Macromolecules,1993,26 (11):2663-2669.
  • 7Cais R E,Kometani J M.New isomers of poly(vinyl fluoride) with controlled regiosequence microstructure[J].Polymer,1988,29(1):168-172.
  • 8Dole,Fluoropolymers M.The radiation chemistry of macromolecules:vol Ⅱ[M].New York:Academic Pres,1973:169.
  • 9Nguyen M T,Hegarty A F.An ab initio study of the ground and excited states of HPO[J].Chemical Physics,1985,98(3):447-453.

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