摘要
合成了一种新的化合物(C6H6C lNO3S)2(H2O)2,测定了其结构.晶体数据表明该配合物属三斜晶系,P-1空间群,晶胞参数为:a=5.8626(8),b=11.7993(17),c=12.7680(18),α=88.286(2)°,β=87.534(2)°,γ=84.121(2)°,V=877.5(2)3,Z=2,Dc=1.708 mg/m3,Rgt(F)=0.0418,wR2(F2)=0.0974,F(000)=464,数据完整度为99.3%,标题化合物含有3种氢键,形成一种三维网状的稳定结构.
The title complex, （（C6H6ClNO3S）2（H2O）2, was synthesized. The crystal structure of the complex was determined by X-ray single crystal diffraction. Its crystal belongs to triclinic with space group P-1, a = 5. 8626 （8） A^°, b =11.7993（17）A^°, c =12.7680（18） A,α =88.286（2）°, β= 87.534（2）°, γ = 84. 121（2）°, V= 877.5（2）A^°3, Z=2, Dc=1.798mg/m^3, F（000） =464, R 1（F） = 0.0418, wR2（F2） = 0.0974. There are three kind of hydrogen bonds, and an extended two-dimensional network of hydrogen bonds contributes to the stabil- ity structure.
出处
《洛阳师范学院学报》
2011年第5期56-58,共3页
Journal of Luoyang Normal University
关键词
3-氨基-4-氯苯磺酸
合成
晶体结构
3-animo-4-chlorobenzenesulphonic acid
synthesis
crystal structure
