摘要
A series of P/HZSM-5 catalysts prepared by impregnation method were used for ethanol conversion to lower olefins. The catalysts were characterized by X-ray diffraction （XRD）, NH3-temperature-programmed desorption （NH3-TPD） and N2 adsorption-desorption measurements. It was found that the P/HZSM-5 catalysts showed high activity and selectivity toward light olefins. The selectivities of propylene and butylene can be improved with the introduction of phosphorus （P）. When the content of P reached 3.0 wt%, more than 18.9% propylene in the gaseous products was obtained over the P/HZSM-5 catalyst at 450 ？C. The introduction of P modified the strong Br？nsted acid sites of the original HZSM-5 catalysts and P/HZSM-5 catalysts could resist coke formation and showed good stability.
A series of P/HZSM-5 catalysts prepared by impregnation method were used for ethanol conversion to lower olefins. The catalysts were characterized by X-ray diffraction （XRD）, NH3-temperature-programmed desorption （NH3-TPD） and N2 adsorption-desorption measurements. It was found that the P/HZSM-5 catalysts showed high activity and selectivity toward light olefins. The selectivities of propylene and butylene can be improved with the introduction of phosphorus （P）. When the content of P reached 3.0 wt%, more than 18.9% propylene in the gaseous products was obtained over the P/HZSM-5 catalyst at 450 ？C. The introduction of P modified the strong Br？nsted acid sites of the original HZSM-5 catalysts and P/HZSM-5 catalysts could resist coke formation and showed good stability.
基金
supported by the Doctor Fund of Science Research of Xinjiang University (Grant No. BS060101)
the National Natural ScienceFoundation of China (Grant No. 20963010)
