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聚苯乙烯/蒙脱土纳米复合材料中的剪切诱导有序结构(Ⅰ)——广角X射线衍射与透射电镜研究 被引量:30

A Shear-induced Ordered Structure in PS/Montmorillonite Nanocomposite(Ⅰ)——Wide Angle X-ray Diffraction and Transmission Electron Microscopy Studies
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摘要 A shear induced ordered structure in PS/montmorillonite nanocomposite was observed for the first time by wide angle X ray diffraction technique. A transmission electron microscopy result showed that the randomly placed primary particles of montmorillonite were oriented parallel to the pellet surface, and the interior of the primary particles became more ordered as well. These results suggested that the orientation of the primary particles as well as the interior ordered structure induced by the shear flow were perhaps the origin of the ordered structure in the PS/montmorillonite nanocomposite. A shear induced ordered structure in PS/montmorillonite nanocomposite was observed for the first time by wide angle X ray diffraction technique. A transmission electron microscopy result showed that the randomly placed primary particles of montmorillonite were oriented parallel to the pellet surface, and the interior of the primary particles became more ordered as well. These results suggested that the orientation of the primary particles as well as the interior ordered structure induced by the shear flow were perhaps the origin of the ordered structure in the PS/montmorillonite nanocomposite.
出处 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 1999年第12期1987-1989,共3页 Chemical Journal of Chinese Universities
基金 国家自然科学基金重点基金!(批准号 :59833310)资助课题
关键词 纳米复合材料 聚苯乙烯 蒙脱土 WAXD TEM Nanocomposite PS Montmorillonite Shear induced ordered structure
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参考文献5

  • 1Ke Yangchuan,J Appl Polym Sci,1999年,71卷,1139页
  • 2Liu Limin,J Appl Polym Sci,1999年,71卷,1133页
  • 3陈光明,高分子通报,1999年
  • 4Wang Shengjie,J Appl Polym Sci,1998年,69卷,15页
  • 5漆宗能,中国发明专利:98103038.6,1998年

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