摘要
Two coordination compounds [Pb4（BDT）3（OH）2（H2O）4].H2O （1） and [Mn（H20）6]·（HBDT）2.2H2O （2） [H2BDT= 5,5＇-（1,4-phenylene）bis（1H-tetrazole）] had been hydrothermally synthesized. 1 and 2 had been characterized by single-crystal X-ray diffraction, IR, elemental and thermal analyses. Structural analysis reveals that 1 exhibits 2D layer structure extended through BDT with two different coordination modes rings in transverse and vertical. 2 consists of [Mn（H2O）6]2＋, free HBDT and water. In addition, 1 and 2 were explored as luminescent materials and additives to promote the thermal decomposition of ammonium perchlorate by differential scanning calorimetry.
Two coordination compounds [Pb4（BDT）3（OH）2（H2O）4].H2O （1） and [Mn（H20）6]·（HBDT）2.2H2O （2） [H2BDT= 5,5＇-（1,4-phenylene）bis（1H-tetrazole）] had been hydrothermally synthesized. 1 and 2 had been characterized by single-crystal X-ray diffraction, IR, elemental and thermal analyses. Structural analysis reveals that 1 exhibits 2D layer structure extended through BDT with two different coordination modes rings in transverse and vertical. 2 consists of [Mn（H2O）6]2＋, free HBDT and water. In addition, 1 and 2 were explored as luminescent materials and additives to promote the thermal decomposition of ammonium perchlorate by differential scanning calorimetry.
基金
Project supported by the National Natural Science Foundation of China （No. 20873100）, and the Natural Science Foundation of Shaanxi Province （Nos. FF10091, SJ08B09）.
