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激光溅射合成全氯代稠环芳烃

Synthesis of perchlorinated polycyclic aromatic hydrocarbon by laser ablation
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摘要 用激光溅射多相反应体系,以石墨为固体靶,以四氯化碳为气相和液相反应物,合成了一系列全氯代稠环芳烃化合物。分离和表征了其中的八氯萘、十氯蒽、十氯菲、十氯芘。结果表明,激光溅射这一物理方法可以做为一种有效的合成手段。 By laser ablating a heterogeneous reaction system which was consisted of solid graphite, liquid and gaseous tetrachloromethane, some sorts of perchlorinated polycyclic aromatic hydrocar-bon were synthesized. Among that octachloronaphthalene (C\-\{10\}Cl\-8), decachloroanthracene(C\-\{14\}Cl\-\{10\}), decachlorophenanthrene(C\-\{14\}Cl\-\{10\}) and decachlorofluoranthene(C\-\{16\}Cl\-\{10\}) were separated and chara-cterized. The results in this work indicated that laser ablation as a physical method can be used as a kind of effective synthsis means, various products are obtained by plasma reaction.
出处 《河南科学》 1999年第3期246-249,共4页 Henan Science
关键词 激光溅射 等离子体 合成 全氯代稠环芳烃 laser ablation plasma synthesis perchlorinated polycyclic aromatic hydrocarbon
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二级参考文献2

  • 1黄荣彬,自然科学进展,1998年,2期,192页
  • 2黄荣彬,J Am Chem Soc,1997年,119卷,25期,5954页

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