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Simultaneous Determination of Halogen Compounds and Sulfur Oxides in Flue Gas by Ion Chromatography 被引量:1

Simultaneous Determination of Halogen Compounds and Sulfur Oxides in Flue Gas by Ion Chromatography
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摘要 Ion chromatography (IC) is a suitable analytical method for the determination of anions. As analytical methods for the halogen compounds in flue gas, those of bromine compound, fluorine compound, chlorine (Cl2) and hydrogen chloride (HCI) are listed in JIS. However, IC has not been adopted in JIS except for HCI and C12. Because the carbon dioxide in flue gas is absorbed in a 0.1 M sodium hydroxide solution as an absorber, it is interfered with the measurement of F^- and Cl^- ions. This paper describes the development of the pretreatment equipment for the flue gas analysis by IC, and its applications to real flue gas analysis. The F^-, Cl^-, Br^- and SO4^2- in the absorbing solution can be clearly separated by IC using the pretreatment equipment. The halogen compounds and sulfur oxides in flue gas can be simultaneously determined by IC.
出处 《Journal of Chemistry and Chemical Engineering》 2011年第4期289-295,共7页 化学与化工(英文版)
关键词 Fluorine compound chloride compound sulfur oxide flue gas analysis ion chromatography 离子色谱法 卤素化合物 烟气分析 硫氧化物 同时测定 氢氧化钠溶液 溴化合物 前处理设备
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  • 2JIS K 0104, Methods for Determination of Nitrogen Oxides in Flue Gas, Japanese Standards Association, Tokyo, 2000.
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  • 10M. Nonomura, T. Hobo, E. Kobayashi, T. Murayama, M.Satoda, Ion chromatographic determination of nitrogen monooxide and nitrogen dioxide after collection in absorption bottle, J. Chromatogr. A 739 (1996) 301.

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