Synthesis of cyclicβ-silylenones via oxidative rearrangement of tertiaryα-hydroxy allylsilanes with PCC

Synthesis of cyclicβ-silylenones via oxidative rearrangement of tertiaryα-hydroxy allylsilanes with PCC

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摘要 An oxidative rearrangement of cyclic tertiary a-hydroxy allylsilanes has been carried out in refluxing ClCH_2CH_2Cl with pyridinium chlorochromate（PCC）.The reaction provides a convenient method to synthesize cyclicβ-silylenones in modest to excellent yields. An oxidative rearrangement of cyclic tertiary a-hydroxy allylsilanes has been carried out in refluxing ClCH_2CH_2Cl with pyridinium chlorochromate（PCC）.The reaction provides a convenient method to synthesize cyclicβ-silylenones in modest to excellent yields.

作者 Xia Wu Jian Lei Zhen Lei Song

机构地区 Key Laboratory of Drug-Targeting of Education Ministry and Department of Medicinal Chemistry

出处《Chinese Chemical Letters》 SCIE CAS CSCD 2011年第3期306-309,共4页 中国化学快报（英文版）

基金 supported by the National Natural Science Foundation of China(No20802044) RFDP(No 200806101091)

关键词 Pyridinium chlorochromate Oxidative rearrangement Cyclicβ-silylenones Pyridinium chlorochromate Oxidative rearrangement Cyclicβ-silylenones

分类号 TQ132.32 [化学工程—无机化工] X503.23 [环境科学与工程—环境工程]

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Chinese Chemical Letters

2011年第3期

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Synthesis of cyclicβ-silylenones via oxidative rearrangement of tertiaryα-hydroxy allylsilanes with PCC

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