摘要
溴丙炔与含活性亚甲基的丙二酸酯反应,合成了14个4-取代-1,6-庚二炔类化合物,其结构经1H NMR确证;4-二苯基磷酰基-4-乙酯基-1,6-庚二炔未见文献报道,其结构经1H NMR,13C NMR,IR和HR-MS表征。
Fourteen 4-substituted-1,6-heptadiyne compounds were synthesized by the reaction between propagyl bromide and malonic ester with active methylene.The structures were confirmed by 1H NMR.The structure of 4-diphenylphosphoryl-4-ethoxycarbonyl-1,6-heptadiyne（new compound） was characterized by 1H NMR,13C NMR,IR and HR-MS.
出处
《合成化学》
CAS
CSCD
北大核心
2011年第1期95-98,共4页
Chinese Journal of Synthetic Chemistry
基金
国家自然科学基金资助项目(20572094)
关键词
1
6-庚二炔
溴丙炔
合成
1
6-heptadiyne
propagyl bromide
synthesis
