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焦油裂解循环灰的催化失活研究 被引量:1

INVESTIGATION OF THE DEACTIVATY OF A KIND OF CIRCULATING ASH WHEN THE TAR CRACKING OVER IT
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摘要 在固定床反应器实验台上以焦油的两种主要组份苯和甲苯为对象,实验研究了焦油裂解过程中一种循环灰的催化失活特性,测定了该种循环灰条件下的失活系数,探讨了循环灰的失活机理.实验结果表明,裂解过程中随着积碳量的增加,裂解反应速率下降。 With the object of two main components of tar: benzene and toluene, the deactivaty of a kind of circulating ash of CFBB for coking is investigated in a fixed bed reactor. The deactivate parameters of this circulating ash were measured and the deactivate mechanic was also discussed. The experimental results proved that with the increasing of coke content in ash the tar cracks slowly, it coursed the yield of coke increasing.
出处 《工程热物理学报》 EI CAS CSCD 北大核心 1999年第5期637-641,共5页 Journal of Engineering Thermophysics
基金 国家科委"八五"攻关项目 清华大学煤清洁燃烧技术国家重点实验室开放基金
关键词 循环灰 焦油组份 失活 积碳 煤燃烧 circulating ash, tar components, deactivate, coke
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参考文献4

  • 1吕俊复,清华大学学报,1998年,38卷,7期,66页
  • 2吕俊复,燃烧学学术会议论文集,1997年
  • 3Chang C C,博士学位论文,1986年
  • 4Lai Chin Kin Steven,博士学位论文,1986年

同被引文献10

  • 1张晓东,周劲松,骆仲泱,陈花,孙立.催化裂化生物质焦油构成变化[J].燃料化学学报,2005,33(5):582-585. 被引量:23
  • 2AZNER P M, CABALLERO M A, GIL J, MARTIN J A, CORELLA J. Commerical steam reforming catalysts to improve biomass gasification with steam-oxygen mixtures[J]. Ind Eng Chem Res, 1998, 37(7) : 2668-2680.
  • 3DELGADO J, AZNER M P, CORELLA J. Biomass gasification with steam in fluidized bed:Effectiveness of CaO, MgO and CaO-MgO for hot raw gas cleaning[J], lnd Eng Chem Res, 1997, 36(5) : 1535-1543.
  • 4DEVI L, CRAJE M, THUNE P. Olivine as tar removal catalyst for biomass gasifiers: Catalyst characterization[ J ]. Appl Catal A, 2005, 294( 1 ) : 68-79.
  • 5ZHANG R, WANG Y, BROW N. Steam reforming of tar compounds over Ni/olivine catalysts doped with CeO2 [ J ]. Energy Convcrs Manage, 2007,48 (1 ) : 68-77.
  • 6BANGALA D N, ABATZOGLOU N, MARTIN J P, CHORNET E. Catalytic gas conditioning: Application to biomass and waste gasification[J]. Ind Eng Chem Res, 1997, 36(10) : 4184-4192.
  • 7DEVI L, PTASINSKI K J, JANSSEN F J J G. Pretreated olivine as tar removal catalyst for biomass gasifiers: Investigation using naphthalene as model biomass tar[ J]. Fuel Process Technol, 2005, 86(6) : 707-730.
  • 8庞克亮,赵长遂,林良生,向文国.天然焦的XRD及气化特性[J].燃料化学学报,2007,35(3):268-272. 被引量:17
  • 9王晨光,王铁军,吕鹏梅,常杰,徐莹.整体式催化剂催化重整净化生物质粗燃气性能研究[J].燃料化学学报,2007,35(3):285-288. 被引量:12
  • 10周劲松,王铁柱,骆仲泱,张晓东,王树荣,岑可法.生物质焦油的催化裂解研究[J].燃料化学学报,2003,31(2):144-148. 被引量:83

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