摘要
以Brnsted-Lewis酸性离子液体为催化剂,用于催化生物柴油中不饱和脂肪酸甲酯聚合制备二聚酸甲酯反应,考察了催化剂种类、催化剂用量、反应温度和时间等因素对聚合反应性能的影响,得到较佳的反应条件.结果表明,当以1-(3-磺酸)-丙基-3-甲基咪唑氯锌酸盐[HO3S-(CH2)3-mim]Cl-ZnCl2(ZnCl2摩尔分数为0.67)为催化剂,生物柴油15g,m(生物柴油):m(离子液体)=15:1,于240oC下反应6h时,二聚酸甲酯收率为63.2%,其中三聚体含量小于5%.另外,该催化剂重复使用5次后,二聚酸甲酯收率仍超过63%,表明其具有较好的重复使用性能.离子液体的Brnsted和Lewis酸位的协同效应显著提高了其催化活性.
The polymerization of fatty acid methyl ester was investigated using biodiesel as the feed in the presence of a Brnsted-Lewis acidic ionic liquid （IL）. A synergetic effect of Brnsted and Lewis acid sites enhanced the catalytic performance of the IL. 1-（3-Sulfonic acid）-propyl-3-methylimidazole chlorozincinate （[HO3S-（CH2）3-mim]Cl-ZnCl2,molar fraction of ZnCl2 was 0.67） was an efficient catalyst for the polymerization. The effects of catalyst amount,reaction temperature,and reaction time were investigated. The optimum conditions for the polymerization were：biodiesel 15 g,m（biodiesel）：m（IL） = 15：1,reaction temperature 240 oC,and reaction time 6 h,which gave 63.2% yield of dimeric acid methyl ester. The reusability of the IL was good and after it was used five times,the dimeric acid methyl ester yield was still 63%.
出处
《催化学报》
SCIE
EI
CAS
CSCD
北大核心
2010年第12期1433-1438,共6页
基金
国家自然科学基金(30571463)
山东省博士基金(BS2010NJ006)
关键词
酸性离子液体
生物柴油
脂肪酸甲酯
聚合
二聚酸甲酯
acidic ionic liquid
biodiesel
fatty acid methyl ester
polymerization
dimeric acid methyl ester
