摘要
trans 1,4 Polybutadiene(PTBD) was synthesized by rare earth catalyst system. The effect of electron radiation on phase transition from monoclinic phase to hexagonal phase was observed by TEM. Electron diffraction patterns of monoclinic phase, hexagonal phase and two coexistent phases were recorded. The mechanism of phase transition was also discussed in this paper.
trans 1,4 Polybutadiene(PTBD) was synthesized by rare earth catalyst system. The effect of electron radiation on phase transition from monoclinic phase to hexagonal phase was observed by TEM. Electron diffraction patterns of monoclinic phase, hexagonal phase and two coexistent phases were recorded. The mechanism of phase transition was also discussed in this paper.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
1999年第11期1811-1812,共2页
Chemical Journal of Chinese Universities
基金
国家科技部基础研究重大关键项目
国家自然科学基金
关键词
电子辐照
晶型
相态转变
反式
聚丁二烯
PTBD
Electron radiation, trans 1,4 Polybutadiene, Crystal structure, Phase transition
