摘要
利用氧化偶联反应，由对苯二胺与端胺基被保护的苯胺二聚体， 合成了包含苯胺五聚体的电活性大单体， 这条合成路线的特点是，保护了苯胺二聚体的胺端基，防止其进一步反应。利用缩聚反应，由己二胺和１ ，１２ － 十二二胺与大单体合成了电活性聚合物。
Electroactive macromonomer a was synthesized by the oxidative coupling reaction of p-phenylene-diamine and b. This synthetic route protected the amine terminal group of N-phenyl-1,4-phenylenediamine from further reactions. Electroactive copolymers was synthesized by means of polycondensation from the macromonomer and 1,12-diaminododecane or 1,6-hexanediamine. The macromonomer was characterized with IR, MS and NMR. The electroactivity of the macromonomer and copolymers were studied by UV and CV.
出处
《功能高分子学报》
CAS
CSCD
1999年第3期269-272,共4页
Journal of Functional Polymers
基金
国家自然科学基金
关键词
聚苯胺
齐聚物
氧化偶联
电活性聚合物
大单体
polyaniline
oxidative coupling reaction
oligomers
eclectroactive polymer
