摘要
Organo lanthanide complex (C 5Me 5)NdCl 2·LiCl has been found to be an efficient catalyst for the hydrogenation of nanometric magnesium powder. This magnesium powder was generated by the thermal decomposition of magnesium anthracene in THF at 90～150 ℃ under vacuum. Suitable temperatures for the catalytic hydrogenation of nanometric magnesium powder are between 150～185 ℃ which are much lower than that of the nanometric magnesium powder without catalyst.
Organo lanthanide complex (C 5Me 5)NdCl 2·LiCl has been found to be an efficient catalyst for the hydrogenation of nanometric magnesium powder. This magnesium powder was generated by the thermal decomposition of magnesium anthracene in THF at 90～150 ℃ under vacuum. Suitable temperatures for the catalytic hydrogenation of nanometric magnesium powder are between 150～185 ℃ which are much lower than that of the nanometric magnesium powder without catalyst.
出处
《催化学报》
SCIE
CAS
CSCD
北大核心
1999年第5期491-492,共2页
关键词
纳米
镁粉
稀土配合物
蒽镁
加氢
催化剂
茂基
nanometric magnesium powder, lanthanide complex, magnesium anthracene, thermal decomposition, catalytic hydrogenation
