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两相法合成取代水杨酸二茂钛配合物 被引量:3

An Interfacial Method for Preparation of Biscyclopentadienyltitanium(Ⅳ) Salicylic Complexes
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摘要 An interfacial method of synthesizing the complexes of titanocene with substituted salicylic acid is reported. The complexes are characterized by elemental analysis, IR and 1H NMR spectra. According to the spectroscopic data, it is suggested that the hydroxyl and carboxyl oxygen in substituted salicylic acid are bound to Ti of titanocene forming hexacyclic compound. An interfacial method of synthesizing the complexes of titanocene with substituted salicylic acid is reported. The complexes are characterized by elemental analysis, IR and 1H NMR spectra. According to the spectroscopic data, it is suggested that the hydroxyl and carboxyl oxygen in substituted salicylic acid are bound to Ti of titanocene forming hexacyclic compound.
作者 高子伟
出处 《应用化学》 CAS CSCD 北大核心 1999年第4期89-90,共2页 Chinese Journal of Applied Chemistry
关键词 二茂钛 水杨酸配合物 两相合成法 环状化合物 titanocene,salicylic complex,interfacial synthesis
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  • 1Zhigang Zhang,Pin Yang,Maolin Guo. Study of interactions between titanocene dichloride and mononucleotides by high-resolution 1H- and 31P-nuclear magnetic resonance[J] 1996,Transition Metal Chemistry(4):322~326

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